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Hydroalkynylative cyclization of 1,6-enynes with terminal alkynes
A rhodium-catalyzed highly regio- and enantioselective hydroalkynylation, generating cis-hydrobenzofuranone-tethered enynes has been developed. The reaction proceeds with a selective head-to-head insertion and symmetry breaking Michael addition cascade. One product was produced from tens of possible...
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| 出版年: | Chem Sci |
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| 主要な著者: | , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
Royal Society of Chemistry
2019
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6657412/ https://ncbi.nlm.nih.gov/pubmed/31391909 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc02341k |
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