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Intermolecular rhodium-catalyzed [2 + 2 + 2] carbocyclization reactions of 1,6-enynes with symmetrical and unsymmetrical alkynes

The crossed intermolecular rhodium-catalyzed [2 + 2 + 2] carbocyclization of carbon and heteroatom tethered 1,6-enynes can be accomplished with symmetrical and unsymmetrical alkynes, to afford the corresponding bicyclohexadienes in an efficient and highly selective manner.

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Hlavní autoři: Andrew Evans, P., Sawyer, James R., Lai, Kwong Wah, Huffman, John C.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2005
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC1475740/
https://ncbi.nlm.nih.gov/pubmed/16075089
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/b505383h
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