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Effect of Ester on Rhodium-Catalyzed Intermolecular [5 + 2] Cycloaddition of 3-Acyloxy-1,4-enynes and Alkynes

We systematically examined the effect of different esters for the rhodium-catalyzed intermolecular [5 + 2] cycloaddition of 3-acyloxy-1,4-enynes and alkynes with a concomitant 1,2-acyloxy migration. Significant rate acceleration was observed for benzoate substrates bearing an electron-donating subst...

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Detalhes bibliográficos
Main Authors: Schienebeck, Casi M., Robichaux, Patrick J., Li, Xiaoxun, Chen, Lianqing, Tang, Weiping
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3610414/
https://ncbi.nlm.nih.gov/pubmed/23435501
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c3cc40634b
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