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Effect of Ester on Rhodium-Catalyzed Intermolecular [5 + 2] Cycloaddition of 3-Acyloxy-1,4-enynes and Alkynes
We systematically examined the effect of different esters for the rhodium-catalyzed intermolecular [5 + 2] cycloaddition of 3-acyloxy-1,4-enynes and alkynes with a concomitant 1,2-acyloxy migration. Significant rate acceleration was observed for benzoate substrates bearing an electron-donating subst...
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| Auteurs principaux: | , , , , |
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| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2013
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3610414/ https://ncbi.nlm.nih.gov/pubmed/23435501 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c3cc40634b |
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