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Rhodium-Catalyzed Stereoselective Intramolecular [5 + 2] Cy-cloaddition of 3-Acyloxy-1,4-enyne and Alkene
[Image: see text] The first rhodium-catalyzed intramolecular [5 + 2] cycloaddition of 3-acyloxy-1,4-enyne and alkene was developed. The cycloaddition is highly diastereoselective in most cases. Various cis-fused bicyclo[5.3.0]decadienes were prepared stereoselectively. The chirality in the propargyl...
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| Izdano u: | Org Lett |
|---|---|
| Glavni autori: | , , , , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2015
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4610816/ https://ncbi.nlm.nih.gov/pubmed/26440751 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.5b02665 |
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