Rhodium-Catalyzed Stereoselective Intramolecular [5 + 2] Cy-cloaddition of 3-Acyloxy-1,4-enyne and Alkene

[Image: see text] The first rhodium-catalyzed intramolecular [5 + 2] cycloaddition of 3-acyloxy-1,4-enyne and alkene was developed. The cycloaddition is highly diastereoselective in most cases. Various cis-fused bicyclo[5.3.0]decadienes were prepared stereoselectively. The chirality in the propargyl...

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Bibliographic Details
Published in:Org Lett
Main Authors: Shu, Xing-zhong, Schienebeck, Casi M., Li, Xiaoxun, Zhou, Xin, Song, Wangze, Chen, Lianqing, Guzei, Ilia A., Tang, Weiping
Format: Artigo
Language:Inglês
Published: 2015
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC4610816/
https://ncbi.nlm.nih.gov/pubmed/26440751
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.5b02665
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