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Rhodium-Catalyzed Intermolecular [5+1] and [5+2] Cycloadditions Using 1,4-Enynes with an Electron-Donating Ester on the 3-Position

Various 3-acyloxy-1,4-enynes could be employed in rhodium-catalyzed intermolecular [5+1] and [5+2] cycloadditions with CO or alkynes, respectively. The rate of these cycloadditions could be accelerated significantly by using 1,4-enynes with an electron-donating ester on the 3-position. The scope of...

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Detalhes bibliográficos
Publicado no:Synthesis (Stuttg)
Main Authors: Schienebeck, Casi M., Song, Wangze, Smits, Angela M., Tang, Weiping
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4617232/
https://ncbi.nlm.nih.gov/pubmed/26508806
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1055/s-0034-1380160
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