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Ligand‐Controlled Diastereoselective Cobalt‐Catalysed Hydroalkynylation of Terminal Alkynes to E‐ or Z‐1,3‐Enynes

A diastereoselective hydroalkynylation of terminal alkynes to form the head‐to‐head dimerization products by two different cobalt‐phosphine catalyst system is reported. The use of the bidentate ligand dppp and additional triphenylphosphine led to the selective formation of the (E)‐1,3‐enynes (E:Z>...

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Détails bibliographiques
Publié dans:Chemistry
Auteurs principaux: Weber, Sebastian M., Queder, Jona, Hilt, Gerhard
Format: Artigo
Langue:Inglês
Publié: John Wiley and Sons Inc. 2020
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC7540399/
https://ncbi.nlm.nih.gov/pubmed/32271963
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202001697
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