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Ligand‐Controlled Diastereoselective Cobalt‐Catalysed Hydroalkynylation of Terminal Alkynes to E‐ or Z‐1,3‐Enynes
A diastereoselective hydroalkynylation of terminal alkynes to form the head‐to‐head dimerization products by two different cobalt‐phosphine catalyst system is reported. The use of the bidentate ligand dppp and additional triphenylphosphine led to the selective formation of the (E)‐1,3‐enynes (E:Z>...
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| Publicat a: | Chemistry |
|---|---|
| Autors principals: | , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
John Wiley and Sons Inc.
2020
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7540399/ https://ncbi.nlm.nih.gov/pubmed/32271963 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202001697 |
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