Synthesis of Fulvene Vinyl Ethers by Gold Catalysis

Gold‐catalyzed cyclization of 1,5‐diynes with ketones as reagents and solvent provides diversely substituted vinyl ethers under mild conditions. The regioselectivity of such gold‐catalyzed cyclizations is usually controlled by the scaffold of the diyne. Herein, we report the first solvent‐controlled...

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Publicat a:Chemistry
Autors principals: Ahrens, Alexander, Schwarz, Julia, Lustosa, Danilo M., Pourkaveh, Raheleh, Hoffmann, Marvin, Rominger, Frank, Rudolph, Matthias, Dreuw, Andreas, Hashmi, A. Stephen K.
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2020
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7216831/
https://ncbi.nlm.nih.gov/pubmed/32092204
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000338
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