Synthesis of Fulvene Vinyl Ethers by Gold Catalysis

Gold‐catalyzed cyclization of 1,5‐diynes with ketones as reagents and solvent provides diversely substituted vinyl ethers under mild conditions. The regioselectivity of such gold‐catalyzed cyclizations is usually controlled by the scaffold of the diyne. Herein, we report the first solvent‐controlled...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Ahrens, Alexander, Schwarz, Julia, Lustosa, Danilo M., Pourkaveh, Raheleh, Hoffmann, Marvin, Rominger, Frank, Rudolph, Matthias, Dreuw, Andreas, Hashmi, A. Stephen K.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7216831/
https://ncbi.nlm.nih.gov/pubmed/32092204
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000338
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