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Gold(I) Complexes Stabilized by Nine‐ and Ten‐Membered N‐Heterocyclic Carbene Ligands

Nine‐ and ten‐membered N‐heterocyclic carbene (NHC) ligands have been developed and for the first time their gold(I) complexes were synthesized. The protonated NHC pro‐ligands 2 a–h were prepared by the reaction of readily available N,N′‐diarylformamidines with bis‐electrophilic building blocks, fol...

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Publicat a:Chemistry
Autors principals: Cervantes‐Reyes, Alejandro, Rominger, Frank, Rudolph, Matthias, Hashmi, A. Stephen K.
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2019
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6852534/
https://ncbi.nlm.nih.gov/pubmed/31310385
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201902458
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