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Sterically Demanding Ag(I) and Cu(I) N‐Heterocyclic Carbene Complexes: Synthesis, Structures, Steric Parameters, and Catalytic Activity

The synthesis and full characterization of new air‐stable Ag(I) and Cu(I) complexes bearing structurally bulky expanded‐ring N‐heterocyclic carbene (erNHC) ligands is presented. The condensation of protonated NHC salts with Ag(2)O afforded a collection of Ag(I) complexes, and their first use as liga...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Cervantes‐Reyes, Alejandro, Rominger, Frank, Hashmi, A. Stephen K.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7216994/
https://ncbi.nlm.nih.gov/pubmed/32104933
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000600
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