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Ambient gold-catalyzed O-vinylation of cyclic 1,3-diketone: A vinyl ether synthesis

Gold-catalyzed O-vinylation of cyclic 1,3-diketones has been achieved for the first time, which provides direct access to various vinyl ethers. A catalytic amount of copper triflate was identified as the significant additive in promoting this transformation. Both aromatic and aliphatic alkynes are s...

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Détails bibliographiques
Auteurs principaux: Xi, Yumeng, Dong, Boliang, Shi, Xiaodong
Format: Artigo
Langue:Inglês
Publié: Beilstein-Institut 2013
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC3869262/
https://ncbi.nlm.nih.gov/pubmed/24367417
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.9.288
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