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Ambient gold-catalyzed O-vinylation of cyclic 1,3-diketone: A vinyl ether synthesis
Gold-catalyzed O-vinylation of cyclic 1,3-diketones has been achieved for the first time, which provides direct access to various vinyl ethers. A catalytic amount of copper triflate was identified as the significant additive in promoting this transformation. Both aromatic and aliphatic alkynes are s...
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| Hauptverfasser: | , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
Beilstein-Institut
2013
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3869262/ https://ncbi.nlm.nih.gov/pubmed/24367417 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.9.288 |
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