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Enantio- and Diastereoselective Synthesis of Homoallylic α‑Trifluoromethyl Amines by Catalytic Hydroalkylation of Dienes
We describe a strategy for the enantio- and diastereoselective synthesis of homoallylic α-trifluoromethyl amines by the catalytic hydroalkylation of terminal dienes. Trifluoromethyl-substituted isatin-derived azadienolate nucleophiles undergo γ-selective alkylation with a Pd–DTBM-SEGPHOS catalyst, w...
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| Publicado no: | Org Lett |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7079280/ https://ncbi.nlm.nih.gov/pubmed/32013445 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.0c00342 |
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