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Accounting for Strong Ligand Sensitivity in Pd-Catalyzed α-Arylation of Enolates from Ketones, Esters, and Nitroalkanes
The mechanism of the Pd-catalyzed α-arylation of three model enolates is studied focusing on a analysis of their very different reactivity. In particular, the low reactivity of nitronates under standard arylation conditions and their high sensitivity to the nature of catalytic system is addressed. T...
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| Pubblicato in: | J Org Chem |
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| Autori principali: | , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2020
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7061083/ https://ncbi.nlm.nih.gov/pubmed/31994879 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.9b03203 |
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