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Accounting for Strong Ligand Sensitivity in Pd-Catalyzed α-Arylation of Enolates from Ketones, Esters, and Nitroalkanes
The mechanism of the Pd-catalyzed α-arylation of three model enolates is studied focusing on a analysis of their very different reactivity. In particular, the low reactivity of nitronates under standard arylation conditions and their high sensitivity to the nature of catalytic system is addressed. T...
Shranjeno v:
| izdano v: | J Org Chem |
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| Main Authors: | , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2020
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7061083/ https://ncbi.nlm.nih.gov/pubmed/31994879 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.9b03203 |
| Oznake: |
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