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Stereoselective Multicomponent Reactions Using Zincate Nucleophiles: β-Dicarbonyl Synthesis and Functionalization
A general strategy for conjugate addition–C-acylation that enables the synthesis of enantioenriched β-dicarbonyl compounds is described. A novel method for derivatizing these adducts by stereo- and site-selective zinc-catalyzed addition of alkyllithium reagents is also reported. These reactions can...
Enregistré dans:
| Publié dans: | Org Lett |
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| Auteurs principaux: | , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2016
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7000105/ https://ncbi.nlm.nih.gov/pubmed/27670226 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.6b02320 |
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