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Stereoselective Multicomponent Reactions Using Zincate Nucleophiles: β-Dicarbonyl Synthesis and Functionalization

A general strategy for conjugate addition–C-acylation that enables the synthesis of enantioenriched β-dicarbonyl compounds is described. A novel method for derivatizing these adducts by stereo- and site-selective zinc-catalyzed addition of alkyllithium reagents is also reported. These reactions can...

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Detalhes bibliográficos
Publicado no:Org Lett
Main Authors: Murphy, Stephen K., Zeng, Mingshuo, Herzon, Seth B.
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7000105/
https://ncbi.nlm.nih.gov/pubmed/27670226
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.6b02320
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