Načítá se...
Formation of a Reactive, Alkyl Thiolate-Ligated Fe(III)-Superoxo Intermediate Derived from Dioxygen
Herein, we describe an alkyl thiolate-ligated iron complex that reacts with dioxygen to form an unprecedented example of an iron superoxo (O(2)(•−)) intermediate, [Fe(III)(S(2)(Me2)N(3)(Pr,Pr))(O(2))] (4), which is capable of cleaving strong C–H bonds. A cysteinate-ligated iron superoxo intermediate...
Uloženo v:
| Vydáno v: | J Am Chem Soc |
|---|---|
| Hlavní autoři: | , , , , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2019
|
| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6942688/ https://ncbi.nlm.nih.gov/pubmed/30661357 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b12670 |
| Tagy: |
Přidat tag
Žádné tagy, Buďte první, kdo otaguje tento záznam!
|