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Metal-Assisted Oxo Atom Addition to an Fe(III) Thiolate
Cysteinate oxygenation is intimately tied to the function of both cysteine dioxygenases (CDOs) and nitrile hydratases (NHases), and yet the mechanisms by which sulfurs are oxidized by these enzymes are unknown, in part because intermediates have yet to be observed. Herein, we report a five-coordinat...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5262503/ https://ncbi.nlm.nih.gov/pubmed/28033001 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b03512 |
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