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Metal-Assisted Oxo Atom Addition to an Fe(III) Thiolate

Cysteinate oxygenation is intimately tied to the function of both cysteine dioxygenases (CDOs) and nitrile hydratases (NHases), and yet the mechanisms by which sulfurs are oxidized by these enzymes are unknown, in part because intermediates have yet to be observed. Herein, we report a five-coordinat...

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Bibliografski detalji
Izdano u:J Am Chem Soc
Glavni autori: Villar-Acevedo, Gloria, Lugo-Mas, Priscilla, Blakely, Maike N., Rees, Julian A., Ganas, Abbie S., Hanada, Erin M., Kaminsky, Werner, Kovacs, Julie A
Format: Artigo
Jezik:Inglês
Izdano: 2016
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5262503/
https://ncbi.nlm.nih.gov/pubmed/28033001
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b03512
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