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Steric and Electronic Control over the Reactivity of a Thiolate-Ligated Fe(II) Complex with Dioxygen and Superoxide: Reversible μ-Oxo Dimer Formation
The reactivity between a thiolate-ligated five-coordinate complex [Fe(II)(S(Me2)N(4)(tren))](+) (1) and dioxygen is examined in order to determine if O(2) activation, resembling that of the metalloenzyme cytochrome P450, can be promoted even when O(2) binds cis, as opposed to trans, to a thiolate. P...
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| Pubblicato in: | Inorg Chem |
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| Autori principali: | , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2004
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4485619/ https://ncbi.nlm.nih.gov/pubmed/15554633 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic0491884 |
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