Characterization and Dioxygen Reactivity of a New Series of Coordinatively Unsaturated Thiolate-Ligated Manganese(II) Complexes

The synthesis, structural, and spectroscopic characterization of four new coordinatively unsaturated mononuclear thiolate-ligated manganese(II) complexes ([Mn(II)(S(Me2)N(4)(6-Me-DPEN))](BF(4)) (1), [Mn(II)(S(Me2)N(4)(6-Me-DPPN))](BPh(4))•MeCN (3), [Mn(II)(S(Me2)N(4)(2-QuinoPN))](PF(6))•MeCN•Et(2)O...

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Main Authors: Coggins, Michael K., Toledo, Santiago, Shaffer, Erika, Kaminsky, Werner, Shearer, Jason, Kovacs, Julie A.
Formato: Artigo
Idioma:Inglês
Publicado: 2012
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Article
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC3422664/
https://ncbi.nlm.nih.gov/pubmed/22642272
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic300192q
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