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Structural and Spectroscopic Characterization of Metastable Thiolate-Ligated Manganese(III)-Alkylperoxo Species
Metastable Mn-peroxo species are proposed to form as key intermediates in biological oxidation reactions involving O(2) and C–H bond activation. The majority of these have yet to be spectroscopically characterized, and their inherent instability, in most cases, precludes structural characterization....
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2011
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3178334/ https://ncbi.nlm.nih.gov/pubmed/21776951 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja205520u |
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