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Nitrile Hydration by Thiolate–and Alkoxide–Ligated Co-NHase Analogues. Isolation of Co(III)-Amidate and Co(III)–Iminol Intermediates

Nitrile hydratases (NHases) are thiolate–ligated Fe(III)- or Co(III)-containing enzymes, which convert nitriles to the corresponding amide under mild conditions. Proposed NHase mechanisms involve M(III)–NCR, M(III)–OH, M(III)–iminol and M(III)–amide intermediates. Spectroscopic and kinetic data supp...

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Bibliografische gegevens
Hoofdauteurs: Swartz, Rodney D., Coggins, Michael K., Kaminsky, Werner, Kovacs, Julie A.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2011
Onderwerpen:
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3151161/
https://ncbi.nlm.nih.gov/pubmed/21351789
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja108749f
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