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Geometric and Electronic Structure of a Crystallographically Characterized Thiolate-Ligated Binuclear Peroxo-Bridged Cobalt(III) Complex
In order to shed light on metal-dependent mechanisms for O-O bond cleavage, and its microscopic reverse, we compare herein the electronic and geometric structures of O(2)-derived binuclear Co(III)- and Mn(III)-peroxo compounds. Binuclear metal peroxo complexes are proposed to form as intermediates d...
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| Publicado en: | J Biol Inorg Chem |
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| Autores principales: | , , , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2019
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6948190/ https://ncbi.nlm.nih.gov/pubmed/31342141 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s00775-019-01686-x |
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