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Investigation of the Mechanism of Formation of a Thiolate-Ligated Fe(III)-OOH
Kinetic studies aimed at determining the most probable mechanism for the proton-dependent [Fe(II)(S(Me2)N(4)(tren))](+) (1) promoted reduction of superoxide via a thiolate-ligated hydroperoxo intermediate [Fe(III)(S(Me2)N(4)(tren))(OOH)](+) (2) are described. Rate laws are derived for three proposed...
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3374498/ https://ncbi.nlm.nih.gov/pubmed/21284379 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic101776m |
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