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Investigation of the Mechanism of Formation of a Thiolate-Ligated Fe(III)-OOH

Kinetic studies aimed at determining the most probable mechanism for the proton-dependent [Fe(II)(S(Me2)N(4)(tren))](+) (1) promoted reduction of superoxide via a thiolate-ligated hydroperoxo intermediate [Fe(III)(S(Me2)N(4)(tren))(OOH)](+) (2) are described. Rate laws are derived for three proposed...

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Main Authors: Nam, Elaine, Alokolaro, Pauline E., Swartz, Rodney D., Gleaves, Morgan C., Pikul, Jessica, Kovacs, Julie A.
格式: Artigo
語言:Inglês
出版: 2011
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC3374498/
https://ncbi.nlm.nih.gov/pubmed/21284379
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic101776m
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