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Geometric and Electronic Structure of a Crystallographically Characterized Thiolate-Ligated Binuclear Peroxo-Bridged Cobalt(III) Complex

In order to shed light on metal-dependent mechanisms for O-O bond cleavage, and its microscopic reverse, we compare herein the electronic and geometric structures of O(2)-derived binuclear Co(III)- and Mn(III)-peroxo compounds. Binuclear metal peroxo complexes are proposed to form as intermediates d...

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Bibliografski detalji
Izdano u:J Biol Inorg Chem
Glavni autori: Dedushko, Maksym A., Schweitzer, Dirk, Blakely, Maike N., Swartz, Rodney D., Kaminsky, Werner, Kovacs, Julie A.
Format: Artigo
Jezik:Inglês
Izdano: 2019
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6948190/
https://ncbi.nlm.nih.gov/pubmed/31342141
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s00775-019-01686-x
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