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Comparison of Structurally–Related Alkoxide, Amine, and Thiolate–Ligated M(II) (M= Fe, Co) Complexes: the Influence of Thiolates on the Properties of Biologically Relevant Metal Complexes
Mechanistic pathways of metalloenzymes are controlled by the metal ion’s electronic and magnetic properties, which are tuned by the coordinated ligands. The functional advantage gained by incorporating cysteinates into the active site of non-heme iron enzymes such as superoxide reductase (SOR) is no...
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| Huvudupphovsmän: | , , , , , , , |
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| Materialtyp: | Artigo |
| Språk: | Inglês |
| Publicerad: |
2008
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| Ämnen: | |
| Länkar: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3126625/ https://ncbi.nlm.nih.gov/pubmed/21731109 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.ica.2007.07.038 |
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