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Characterization of Metastable Intermediates Formed in the Reaction Between a Mn(II) Complex and Dioxygen, Including a Crystallographic Structure of a Binuclear Mn(III)-Peroxo Species
Transition-metal peroxos have been implicated as key intermediates in a variety of critical biological processes involving O(2). Due to their highly reactive nature, very few metal-peroxos have been characterized. The dioxygen chemistry of manganese remains largely unexplored despite the proposed in...
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3709604/ https://ncbi.nlm.nih.gov/pubmed/23470101 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja311166u |
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