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Factors Influencing Conversion Kinetics of Triply-Bridged (μ-η(1):η(1)-Peroxo)Diiron(III) Intermediates to Doubly-Bridged (μ-η(1):η(1)-Peroxo)Diiron(III) Intermediates
Several [Fe(II) (2)(N-EtHPTB)(μ-O(2)X)](2+) complexes (1•O(2)X) have been synthesized, where N-EtHPTB is the anion of N,N,N′N′-tetrakis(2-benzimidazolylmethyl)-2-hydroxy-1,3-diaminopropane and O(2)X is an oxyanion bridge. Crystal structures reveal five-coordinate (μ-alkoxo)diiron(II) cores. These di...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3678525/ https://ncbi.nlm.nih.gov/pubmed/23432330 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic302543n |
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