Spectroscopic and Computational Studies of (µ-Oxo)(µ-1,2-peroxo)diiron(III) Complexes of Relevance to Nonheme Diiron Oxygenase Intermediates

With the goal of gaining insight into the structures of peroxo intermediates observed for oxygen activating nonheme diiron enzymes, a series of metastable synthetic diiron(III)-peroxo complexes with [Fe(III)(2)(µ-O)(µ-1,2-O(2))] cores has been characterized by X-ray absorption and resonance Raman sp...

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Autori principali: Fiedler, Adam T., Shan, Xiaopeng, Mehn, Mark P., Kaizer, József, Torelli, Stéphane, Frisch, Jonathan R., Kodera, Masahito, Que, Lawrence
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2008
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Article
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC2736334/
https://ncbi.nlm.nih.gov/pubmed/18811130
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp8038225
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