A nonheme peroxo-diiron(iii) complex exhibiting both nucleophilic and electrophilic oxidation of organic substrates

The complex [Fe(III)(2)(μ-O(2))(L(3))(4)(S)(2)](4+) (L(3) = 2-(4-thiazolyl)benzimidazole, S = solvent) forms upon reaction of [Fe(II)(L(3))(2)] with H(2)O(2) and is a functional model of peroxo-diiron intermediates invoked during the catalytic cycle of oxidoreductases. The spectroscopic properties o...

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Detaylı Bibliyografya
Yayımlandı:Dalton Trans
Asıl Yazarlar: Török, Patrik, Unjaroen, Duenpen, Viktória Csendes, Flóra, Giorgi, Michel, Browne, Wesley R., Kaizer, József
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: The Royal Society of Chemistry 2021
Konular:
Chemistry
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC8168641/
https://ncbi.nlm.nih.gov/pubmed/34019062
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1dt01502h
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