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A nonheme peroxo-diiron(iii) complex exhibiting both nucleophilic and electrophilic oxidation of organic substrates
The complex [Fe(III)(2)(μ-O(2))(L(3))(4)(S)(2)](4+) (L(3) = 2-(4-thiazolyl)benzimidazole, S = solvent) forms upon reaction of [Fe(II)(L(3))(2)] with H(2)O(2) and is a functional model of peroxo-diiron intermediates invoked during the catalytic cycle of oxidoreductases. The spectroscopic properties o...
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| 發表在: | Dalton Trans |
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| Main Authors: | , , , , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
The Royal Society of Chemistry
2021
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8168641/ https://ncbi.nlm.nih.gov/pubmed/34019062 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1dt01502h |
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