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Tuning the Relative Stability and Reactivity of Manganese Dioxygen and Peroxo Intermediates via Systematic Ligand Modification

Many fundamental processes of life depend on the chemical energy stored in the O–O bond of dioxygen (O(2)), the majority of which is derived from photosynthetic H(2)O oxidation. Key steps in these processes involve Mn-, Fe-, or Cu-promoted formation or cleavage of O–O and O–H bonds, the mechanisms o...

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Détails bibliographiques
Publié dans:Acc Chem Res
Auteur principal: Kovacs, Julie A.
Format: Artigo
Langue:Inglês
Publié: 2015
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC4888790/
https://ncbi.nlm.nih.gov/pubmed/26335158
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.accounts.5b00260
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