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Tuning the Relative Stability and Reactivity of Manganese Dioxygen and Peroxo Intermediates via Systematic Ligand Modification
Many fundamental processes of life depend on the chemical energy stored in the O–O bond of dioxygen (O(2)), the majority of which is derived from photosynthetic H(2)O oxidation. Key steps in these processes involve Mn-, Fe-, or Cu-promoted formation or cleavage of O–O and O–H bonds, the mechanisms o...
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| Udgivet i: | Acc Chem Res |
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| Hovedforfatter: | |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2015
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4888790/ https://ncbi.nlm.nih.gov/pubmed/26335158 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.accounts.5b00260 |
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