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Formation of a Reactive, Alkyl Thiolate-Ligated Fe(III)-Superoxo Intermediate Derived from Dioxygen
Herein, we describe an alkyl thiolate-ligated iron complex that reacts with dioxygen to form an unprecedented example of an iron superoxo (O(2)(•−)) intermediate, [Fe(III)(S(2)(Me2)N(3)(Pr,Pr))(O(2))] (4), which is capable of cleaving strong C–H bonds. A cysteinate-ligated iron superoxo intermediate...
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| Veröffentlicht in: | J Am Chem Soc |
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| Hauptverfasser: | , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2019
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6942688/ https://ncbi.nlm.nih.gov/pubmed/30661357 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b12670 |
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