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Discovery of a Cryptic Intermediate in Late Steps of Mithramycin Biosynthesis
MtmOIV and MtmW catalyze the final two reactions in the mithramycin (MTM) biosynthetic pathway, the Baeyer-Villiger opening of the fourth ring of premithramycin B (PMB), creating the C3 pentyl side chain, strictly followed by reduction of the distal keto group on the new side chain. Unexpectedly thi...
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| 出版年: | Angew Chem Int Ed Engl |
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| 主要な著者: | , , , , , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2019
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6940538/ https://ncbi.nlm.nih.gov/pubmed/31702856 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201910241 |
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