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How Dihalogens Catalyze Michael Addition Reactions

We have quantum chemically analyzed the catalytic effect of dihalogen molecules (X(2)=F(2), Cl(2), Br(2), and I(2)) on the aza‐Michael addition of pyrrolidine and methyl acrylate using relativistic density functional theory and coupled‐cluster theory. Our state‐of‐the‐art computations reveal that ac...

Deskribapen osoa

Gorde:
Xehetasun bibliografikoak
Argitaratua izan da:Angew Chem Int Ed Engl
Egile Nagusiak: Hamlin, Trevor A., Fernández, Israel, Bickelhaupt, F. Matthias
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: John Wiley and Sons Inc. 2019
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC6617756/
https://ncbi.nlm.nih.gov/pubmed/31033118
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201903196
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