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How Alkali Cations Catalyze Aromatic Diels‐Alder Reactions

We have quantum chemically studied alkali cation‐catalyzed aromatic Diels‐Alder reactions between benzene and acetylene forming barrelene using relativistic, dispersion‐corrected density functional theory. The alkali cation‐catalyzed aromatic Diels‐Alder reactions are accelerated by up to 5 orders o...

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Détails bibliographiques
Publié dans:Chem Asian J
Auteurs principaux: Vermeeren, Pascal, Brinkhuis, Francine, Hamlin, Trevor A., Bickelhaupt, F. Matthias
Format: Artigo
Langue:Inglês
Publié: John Wiley and Sons Inc. 2020
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC7187256/
https://ncbi.nlm.nih.gov/pubmed/32012430
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/asia.202000009
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