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Bifunctional Hydrogen Bond Donor‐Catalyzed Diels–Alder Reactions: Origin of Stereoselectivity and Rate Enhancement

The selectivity and rate enhancement of bifunctional hydrogen bond donor‐catalyzed Diels–Alder reactions between cyclopentadiene and acrolein were quantum chemically studied using density functional theory in combination with coupled‐cluster theory. (Thio)ureas render the studied Diels–Alder cycload...

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Publicado en:Chemistry
Main Authors: Vermeeren, Pascal, Hamlin, Trevor A., Bickelhaupt, F. Matthias, Fernández, Israel
Formato: Artigo
Idioma:Inglês
Publicado: John Wiley and Sons Inc. 2021
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC8049058/
https://ncbi.nlm.nih.gov/pubmed/33169912
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202004496
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