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Origin of rate enhancement and asynchronicity in iminium catalyzed Diels–Alder reactions
The Diels–Alder reactions between cyclopentadiene and various α,β-unsaturated aldehyde, imine, and iminium dienophiles were quantum chemically studied using a combined density functional theory and coupled-cluster theory approach. Simple iminium catalysts accelerate the Diels–Alder reactions by lowe...
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| 出版年: | Chem Sci |
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| 主要な著者: | , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
The Royal Society of Chemistry
2020
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8163289/ https://ncbi.nlm.nih.gov/pubmed/34094173 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc02901g |
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