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Origin of rate enhancement and asynchronicity in iminium catalyzed Diels–Alder reactions

The Diels–Alder reactions between cyclopentadiene and various α,β-unsaturated aldehyde, imine, and iminium dienophiles were quantum chemically studied using a combined density functional theory and coupled-cluster theory approach. Simple iminium catalysts accelerate the Diels–Alder reactions by lowe...

Täydet tiedot

Tallennettuna:
Bibliografiset tiedot
Julkaisussa:Chem Sci
Päätekijät: Vermeeren, Pascal, Hamlin, Trevor A., Fernández, Israel, Bickelhaupt, F. Matthias
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: The Royal Society of Chemistry 2020
Aiheet:
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC8163289/
https://ncbi.nlm.nih.gov/pubmed/34094173
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc02901g
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