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Origin of rate enhancement and asynchronicity in iminium catalyzed Diels–Alder reactions

The Diels–Alder reactions between cyclopentadiene and various α,β-unsaturated aldehyde, imine, and iminium dienophiles were quantum chemically studied using a combined density functional theory and coupled-cluster theory approach. Simple iminium catalysts accelerate the Diels–Alder reactions by lowe...

詳細記述

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書誌詳細
出版年:Chem Sci
主要な著者: Vermeeren, Pascal, Hamlin, Trevor A., Fernández, Israel, Bickelhaupt, F. Matthias
フォーマット: Artigo
言語:Inglês
出版事項: The Royal Society of Chemistry 2020
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC8163289/
https://ncbi.nlm.nih.gov/pubmed/34094173
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc02901g
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