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How Dihalogens Catalyze Michael Addition Reactions

We have quantum chemically analyzed the catalytic effect of dihalogen molecules (X(2)=F(2), Cl(2), Br(2), and I(2)) on the aza‐Michael addition of pyrrolidine and methyl acrylate using relativistic density functional theory and coupled‐cluster theory. Our state‐of‐the‐art computations reveal that ac...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Hamlin, Trevor A., Fernández, Israel, Bickelhaupt, F. Matthias
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6617756/
https://ncbi.nlm.nih.gov/pubmed/31033118
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201903196
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