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How Lewis Acids Catalyze Diels–Alder Reactions

The Lewis acid(LA)‐catalyzed Diels–Alder reaction between isoprene and methyl acrylate was investigated quantum chemically using a combined density functional theory and coupled‐cluster theory approach. Computed activation energies systematically decrease as the strength of the LA increases along th...

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Publicado en:Angew Chem Int Ed Engl
Autores principales: Vermeeren, Pascal, Hamlin, Trevor A., Fernández, Israel, Bickelhaupt, F. Matthias
Formato: Artigo
Lenguaje:Inglês
Publicado: John Wiley and Sons Inc. 2020
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC7187354/
https://ncbi.nlm.nih.gov/pubmed/31944503
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201914582
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