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A regioselectivity switch in Pd-catalyzed hydroallylation of alkynes
By exploiting the reactivity of a vinyl-Pd species, we control the regioselectivity in hydroallylation of alkynes under Pd-hydride catalysis. A monophosphine ligand and carboxylic acid combination promotes 1,5-dienes through a pathway involving isomerization of alkynes to allenes. In contrast, a bis...
Gorde:
| Argitaratua izan da: | Chem Sci |
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| Egile Nagusiak: | , , , , , |
| Formatua: | Artigo |
| Hizkuntza: | Inglês |
| Argitaratua: |
Royal Society of Chemistry
2019
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| Gaiak: | |
| Sarrera elektronikoa: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6598511/ https://ncbi.nlm.nih.gov/pubmed/31341584 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc01527b |
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