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Diastereo- and enantioselective copper catalyzed hydroallylation of disubstituted cyclopropenes
A highly diastereo- and enantioselective protocol for the hydroallylation of 1,1- and 1,2-disubstituted cyclopropenes has been developed utilizing an in situ formed copper hydride. A variety of allyl electrophiles could be utilized yielding a diverse range of trisubstituted cyclopropanes. Finally a...
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| Udgivet i: | Chem Sci |
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| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Royal Society of Chemistry
2018
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6115688/ https://ncbi.nlm.nih.gov/pubmed/30310580 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc02085j |
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