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Diastereo- and enantioselective copper catalyzed hydroallylation of disubstituted cyclopropenes

A highly diastereo- and enantioselective protocol for the hydroallylation of 1,1- and 1,2-disubstituted cyclopropenes has been developed utilizing an in situ formed copper hydride. A variety of allyl electrophiles could be utilized yielding a diverse range of trisubstituted cyclopropanes. Finally a...

詳細記述

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書誌詳細
出版年:Chem Sci
主要な著者: Sommer, Heiko, Marek, Ilan
フォーマット: Artigo
言語:Inglês
出版事項: Royal Society of Chemistry 2018
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC6115688/
https://ncbi.nlm.nih.gov/pubmed/30310580
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc02085j
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