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Cu-Catalyzed Diastereo- and Enantioselective Reactions of γ,γ-Disubstituted Allyldiborons with Ketones

Catalytic diastereo- and enantioselective preparation of complex tertiary homoallylic alcohols containing a vicinal quaternary carbon stereogenic center and a versatile alkenylboronic ester is disclosed. Transformations are promoted by 5 mol % of a readily available copper catalyst bearing a bulky m...

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Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Zanghi, Joseph M., Meek, Simon J.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2020
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC7230022/
https://ncbi.nlm.nih.gov/pubmed/32101637
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202000675
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