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Cu-Catalyzed Diastereo- and Enantioselective Reactions of γ,γ-Disubstituted Allyldiborons with Ketones
Catalytic diastereo- and enantioselective preparation of complex tertiary homoallylic alcohols containing a vicinal quaternary carbon stereogenic center and a versatile alkenylboronic ester is disclosed. Transformations are promoted by 5 mol % of a readily available copper catalyst bearing a bulky m...
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| Pubblicato in: | Angew Chem Int Ed Engl |
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| Autori principali: | , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2020
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7230022/ https://ncbi.nlm.nih.gov/pubmed/32101637 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202000675 |
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