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Diastereo-, Enantio-, and anti-Selective Formation of Secondary Alcohol and Quaternary Carbon Stereocenters by Cu-catalyzed Additions of B-Substituted Allyl Nucleophiles to Carbonyls
A general method for the synthesis of secondary homoallylic alcohols containing α-quaternary carbon stereogenic centers in high diastereo- and enantioselectivity (up to >20:1 dr and >99:1 er) is disclosed. Transformations employ readily accessible aldehydes, allylic diboronates, a chiral coppe...
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| Publicado no: | Org Lett |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7797407/ https://ncbi.nlm.nih.gov/pubmed/33206543 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.0c03495 |
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