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Enantio- and Diastereoselective Synthesis of Functionalized Carbocycles by Cu-Catalyzed Borylative Cyclization of Alkynes with Ketones
A single-pot Cu-catalyzed enantio- and diastereoselective tandem hydroboration/borylative cyclization of alkynes with ketones for the synthesis of carbocycles is reported. The reaction proceeds via a desymmetrization and generates four contiguous stereocenters, including an all-carbon quaternary cen...
Tallennettuna:
| Julkaisussa: | Org Lett |
|---|---|
| Päätekijät: | , , |
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
2019
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| Aiheet: | |
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6702961/ https://ncbi.nlm.nih.gov/pubmed/31199654 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.9b01769 |
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