Carregant...
A regioselectivity switch in Pd-catalyzed hydroallylation of alkynes
By exploiting the reactivity of a vinyl-Pd species, we control the regioselectivity in hydroallylation of alkynes under Pd-hydride catalysis. A monophosphine ligand and carboxylic acid combination promotes 1,5-dienes through a pathway involving isomerization of alkynes to allenes. In contrast, a bis...
Guardat en:
| Publicat a: | Chem Sci |
|---|---|
| Autors principals: | , , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
Royal Society of Chemistry
2019
|
| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6598511/ https://ncbi.nlm.nih.gov/pubmed/31341584 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc01527b |
| Etiquetes: |
Afegir etiqueta
Sense etiquetes, Sigues el primer a etiquetar aquest registre!
|