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Gold-Catalyzed Regioselective Dimerization of Aliphatic Terminal Alkynes
A gold-catalyzed regioselective homodimerization of aliphatic terminal alkynes is described. Bulky and less Lewis acidic tBuXPhosAuNTf(2) is the preferred catalyst, and the additive, anhydrous NaOAc, substantially facilitates the reaction.
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3419542/ https://ncbi.nlm.nih.gov/pubmed/22904604 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1055/s-0031-1289567 |
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