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Chloride-Tolerant Gold(I)-Catalyzed Regioselective Hydrochlorination of Alkynes
[Image: see text] We have developed a highly regioselective homogeneous gold(I)-catalyzed anti-hydrochlorination of unactivated alkynes at room temperature. We have overcome the incompatibility between conventional cationic gold catalysts and chloride by using a hydrogen-bonding activation of the Au...
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| Veröffentlicht in: | ACS Catal |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
American
Chemical Society
2017
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| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5634393/ https://ncbi.nlm.nih.gov/pubmed/29034119 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.7b02567 |
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