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Chloride-Tolerant Gold(I)-Catalyzed Regioselective Hydrochlorination of Alkynes

[Image: see text] We have developed a highly regioselective homogeneous gold(I)-catalyzed anti-hydrochlorination of unactivated alkynes at room temperature. We have overcome the incompatibility between conventional cationic gold catalysts and chloride by using a hydrogen-bonding activation of the Au...

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Detalhes bibliográficos
Publicado no:ACS Catal
Main Authors: Ebule, Rene, Liang, Shengzong, Hammond, Gerald B., Xu, Bo
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2017
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5634393/
https://ncbi.nlm.nih.gov/pubmed/29034119
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.7b02567
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