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A Chlorinating Reagent Yields Vinyl Chlorides with High Regioselectivity under Heterogeneous Gold Catalysis

[Image: see text] A novel chlorinating reagent with a high concentration of HCl has enabled the highly regioselective hydrochlorination of unactivated alkynes using a commercial nanogold catalyst. No overchlorination or hydration products were formed, and various functional groups were tolerated. Th...

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Detalhes bibliográficos
Publicado no:Org Lett
Main Authors: Liang, Shengzong, Ebule, Rene, Hammond, Gerald B., Xu, Bo
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2017
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5586251/
https://ncbi.nlm.nih.gov/pubmed/28809497
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.7b02101
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